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Date:      Tue, 07 Mar 2000 22:40:42 -0500
From:      John <papalia@udel.edu>
To:        David Kelly <dkelly@hiwaay.net>, cjclark@home.com
Cc:        Terry Lambert <tlambert@primenet.com>, Alex Zepeda <jazepeda@pacbell.net>, Olaf Hoyer <ohoyer@fbwi.fh-wilhelmshaven.de>, chat@FreeBSD.ORG
Subject:   Re: Great American Gas Out 
Message-ID:  <4.1.20000307223510.009512b0@mail.udel.edu>
In-Reply-To: <200003080330.VAA09023@nospam.hiwaay.net>
References:  <Message from "Crist J. Clark" <cjc@cc942873-a.ewndsr1.nj.home.com> <20000307213615.A73820@cc942873-a.ewndsr1.nj.home.com>

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>"So, for the same carburetor or fuel injection setting..." tends to
>forget the whole purpose of the O2 sensor is to adjust the mixture.
>Therefore oxygenated fuel is going to affect what the O2 sensor says,
>negating their entire argument and proving the mixture will run richer.

The function of an O2 sensor in your car is to measure "raw" oxygen, as in
"O2" as it's suspended in the atmosphere.  Typically it works as a heated
element.  As it "burns" the oxygen going by, it generates a signal back to
your car's computer, which is in turn converted into a "level" reading.

With MTBE and oxygenated gases, the "oxygenation" is part of a larger
molecule - it is not a free diatomic.  As a result, your oxygen sensor
won't be reading it.  It CAN"T read it based upon the way the O2 sensors
works - it is, in essence, a secondary combustion reaction.

From what I've gathered from (what little) I've actually read about MTBE,
the IDEA behind it is that by having the chemicals infused into the
gasoline, they are able to reduce CO, NOx, and other chemicals.  This *can*
be as simple though as turning CO into CO2.  They don't tell you if CO2 is
increased, decreased, or static.

I've been hunting trying to find a chemical equation which actually shows
the combustion reaction of Gasoline w/ MTBE in it.  No avail so far.  Still
searchign through the scientific journals.

But in the end, Oxygen as it is part of a GREATER molecule does not affect
the O2 sensor of your car.  If this is the case, CO and CO2 (standard
products of combustion) would ALSO effect the sensor.

--John


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